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E10 in airplanes has nothing to do with water. E10 is an unleaded automotive gas. Aircraft engines need leaded fuel to run properly and the lead keeps parts more reliable, it also doesn't vapor lock at high altitudes like car gas
First of all most automotive fuels have a "much" lower octane rating than avgas which is 100LL/low lead. Aircraft engines
require a higher octane to prevent detonation/pinging due to higher performance engines.
Concerning vapor lock the only way to get this situation in an aircraft is on the ground on a very hot day with very little airflow over the engine not at altitude.
You cannot use ethanol fuels in an aircraft/non expreimental class is because water has everything to do w it. Most, not all
piston powered aircraft are "older" carburated engines that fuel runs through a venturi type carburator and is highly succeptable to
freezing, especially at altitude, this is why a/c are equiped w carb heat.